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- The new dz2 and dx2-y2 orbitals don’t have as the direct get in touch with because the ligands sort of squeeze past otherwise fall because of the such orbitals, for this reason lowering the electron-electron repulsion plus the energy of your own orbital.
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Inside the devices of one’s quicker Planck constant ħ, all particles one relocate step 3 dimensions provides sometimes integer spin and you will obey Bose-Einstein analytics or 1 / 2 of-integer twist and you can obey Fermi-Dirac analytics. Because the bromo ligand try a deep failing community ligand , which molecule are large spin. The fresh busting of tetrahedral buildings try individually opposite that the newest breaking of one’s octahedral complexes. Bear in mind you to within the octahedral complexes, the newest dz2 and dx2-y2 orbitals features large time compared to the dxz, dxy, and you may dyz orbitals. Inside tetrahedral complexes, the opposite happen because the dxz, dxy, and dyz orbitals provides high times versus dz2 and dx2-y2 orbitals.
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